The ability to control matter at the atomic scale and build devices with atomic precision is central to nanotechnology. The scanning tunnelling microscope1can manipulate individual atoms2 and molecules on surfaces, but the manipulation of silicon to make atomic-scale logic circuits has been hampered by the covalent nature of its bonds. Resist-based strategies have allowed the formation of atomic-scale structures on silicon surfaces3, but the fabrication of working devices—such as transistors with extremely short gate lengths4, spin-based quantum computers5, 6, 7, 8 and solitary dopant optoelectronic devices9—requires the ability to position individual atoms in a silicon crystal with atomic precision. Here, we use a combination of scanning tunnelling microscopy and hydrogen-resist lithography to demonstrate a single-atom transistor in which an individual phosphorus dopant atom has been deterministically placed within an epitaxial silicon device architecture with a spatial accuracy of one lattice site. The transistor operates at liquid helium temperatures, and millikelvin electron transport measurements confirm the presence of discrete quantum levels in the energy spectrum of the phosphorus atom. We find a charging energy that is close to the bulk value, previously only observed by optical spectroscopy10.
Monday, April 9, 2012
Sunday, April 1, 2012
Inkjet-Printed Graphene Electronics
Felice Torrisi, Tawfique Hasan, Weiping Wu, Zhipei Sun, Antonio Lombardo, Tero S. Kulmala, Gen-Wen Hsieh, Sungjune Jung, Francesco Bonaccorso, Philip J. Paul, Daping Chu, and Andrea C. Ferrari*
Department of Engineering, University of Cambridge, Cambridge CB3 0FA, U.K.
ACS Nano, Article ASAP
DOI: 10.1021/nn2044609
Publication Date (Web): March 9, 2012
Copyright © 2012 American Chemical Society
We demonstrate inkjet printing as a viable method for large-area fabrication of graphene devices. We produce a graphene-based ink by liquid phase exfoliation of graphite in N-methylpyrrolidone. We use it to print thin-film transistors, with mobilities up to
95 cm2 V–1s–1, as well as transparent and conductive patterns, with
80% transmittance and
30 kΩ/□ sheet resistance. This paves the way to all-printed, flexible, and transparent graphene devices on arbitrary substrates.
Observation of Absorption-Dominated Bonding Dark Plasmon Mode from Metal–Insulator–Metal Nanodisk Arrays Fabricated by Nanospherical-Lens Lithography
Yun-Chorng Chang*, Shih-Ming Wang, Hsin-Chan Chung, Chung-Bin Tseng, and Shih-Hui Chang
Department of Photonics and Advanced Optoelectronic Technology Center, National Cheng Kung University, Tainan 701, Taiwan
ACS Nano, Article ASAP
DOI: 10.1021/nn300420x
Publication Date (Web): March 21, 2012
Copyright © 2012 American Chemical Society
Plasmon hybridization modes are observed in the extinction spectra of a metal–insulator–metal (MIM) nanodisk array fabricated using nanospherical-lens lithography. Two distinct hybridization modes are observed in this vertically aligned configuration. Theoretical simulation indicates that the bonding mode located at a lower energy level exhibits an antiphase charge distribution and corresponds to the dark plasmon mode. This is vastly different compared to antibonding dark plasmon mode observed in the conventional dimer configuration. The observed mode is tunable over a wide spectral range simply by varying the insulator thickness and the diameters of the MIM nanodisks. Absorption is the dominating extinction process for the dark plasmon, while scattering dominates the bright plasmon mode. The ability to experimentally measure and tune dark plasmon modes using a MIM configuration should catalyze more novel studies that take full advantages of the absorption-dominated dark plasmon mode.
Directional Photofluidization Lithography: Micro/Nanostructural Evolution by Photofluidic Motions of Azobenzene Materials
- Seungwoo Lee1,3,*,
- Hong Suk Kang2,
- Jung-Ki Park2,3,*
Article first published online: 27 MAR 2012
DOI: 10.1002/adma.201104826
This review demonstrates directional photofluidization lithography (DPL), which makes it possible to fabricate a generic and sophisticated micro/nanoarchitecture that would be difficult or impossible to attain with other methods. In particular, DPL differs from many of the existing micro/nanofabrication methods in that the post-treatment (i.e., photofluidization), after the preliminary fabrication process of the original micro/nanostructures, plays a pivotal role in the various micro/nanostructural evolutions including the deterministic reshaping of architectures, the reduction of structural roughness, and the dramatic enhancement of pattern resolution. Also, DPL techniques are directly compatible with a parallel and scalable micro/nanofabrication. Thus, DPL with such extraordinary advantages in micro/nanofabrication could provide compelling opportunities for basic micro/nanoscale science as well as for general technology applications.
Stretchable Light-Emitting Electrochemical Cells Using an Elastomeric Emissive Material
- Heather L. Filiatrault,
- Gyllian C. Porteous,
- R. Stephen Carmichael,
- Gregory J. E. Davidson,
- Tricia Breen Carmichael*
Article first published online: 26 MAR 2012
DOI: 10.1002/adma.201200448
Dispersing an ionic transition metal complex into an elastomeric matrix enables the fabrication of intrinsically stretchable light-emitting devices that possess large emission areas (∼175 mm2) and tolerate linear strains up to 27% and repetitive cycles of 15% strain. This work demonstrates the suitability of this approach to new applications in conformable lighting that require uniform, diffuse light emission over large areas.
Microfluidic Generation of Acoustically Active Nanodroplets
- Thomas D. Martz1,
- David Bardin2,
- Paul S. Sheeran3,
- Abraham P. Lee2,
- Paul A. Dayton3,*
Article first published online: 29 MAR 2012
DOI: 10.1002/smll.20110241
A microfluidic approach for the generation of perfluorocarbon nanodroplets as the primary emulsion with diameters as small as 300–400 nm is described. The system uses a pressure-controlled delivery of all reagents and increased viscosity in the continuous phase to drive the device into an advanced tip-streaming regime, which results in generation of droplets in the sub-micrometer range. Such nanodroplets may be appropriate for emerging biomedical applications.
Stretchable Semiconductor Technologies with High Areal Coverages and Strain-Limiting Behavior: Demonstration in High-Efficiency Dual-Junction GaInP/GaAs Photovoltaics
- Jongho Lee1,
- Jian Wu2,
- Jae Ha Ryu3,
- Zhuangjian Liu4,
- Matthew Meitl5,
- Yong-Wei Zhang4,
- Yonggang Huang6,
- John A. Rogers7,*
Article first published online: 29 MAR 2012
DOI: 10.1002/smll.201102437
Notched islands on a thin elastomeric substrate serve as a platform for dual-junction GaInP/GaAs solar cells with microscale dimensions and ultrathin forms for stretchable photovoltaic modules. These designs allow for a high degree of stretchability and areal coverage, and they provide a natural form of strain-limiting behavior, helping to avoid destructive effects of extreme deformations.
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